Capps Kincaid (winterhead76)
Cu and Pb were higher in the Little Egret's tissues collected from the agricultural site (S1), whereas Ba, Ni, and Fe were higher in the semi-rural site (S2), followed finally by Cd in the urbanized site (S3). The concentrations of trace elements reported in Little Egrets were within the known background level for water birds. read more However, alarming concentrations were found for Ni levels in liver (from Qillin and Toukh), as well as Pb and Cr levels in kidney samples (from the three localities). MPI of the eleven studied metals in both liver and kidney of the studied species decreased in the order Qillin (24.36) > Abu Rawash (17.98) > Toukh (3.90). In the three investigated localities, the overall calculated MPI values were higher than one, indicating that the ecosystem is polluted. The study suggested using Little Egrets as a bioindicator of metal contamination.This work aims at proposing and validating a model that can be exploited for the future development of industrial applications (e.g., process design and control) of Fenton and photo-Fenton processes. Hence, a compromise modeling solution has been developed between the non-generalizable accuracy of the first principles models (FPMs) and the oversimplification of the empirical models (EMs). The work presents a novel model of moderate complexity that is simplified enough to be generalizable and computationally affordable, while retaining physical meaning. The methodology is based on a general degradation mechanism that can be algorithmically generated from the carbon number of the target compound, as well as from the knowledge of two kinetic parameters, one for the faster initial rate and the other one for the subsequent degradation steps. The contaminant degradation mechanism has been combined with an appropriately simplified implementation of the well-known Fenton and photo-Fenton kinetics. This model describes the degradation not only of the target compound and of the oxidant, but also of total organic carbon (TOC), which is used to define the overall quality of the water. Experimental design techniques were used along with a non-conventional modeling methodology of programmable process structures (PPS). This novel modeling approach was applied and validated on the degradation of three model compounds. A successful prediction of the evolution of the contaminants H2O2 and TOC was confirmed and assessed by the root mean square error (RMSE).This article presents a bibliometric study of 200 European publications released between 2001 and 2016, about the contamination of mushrooms by selected elements. The analysis includes figures on the type of analyte, its concentration, the species of fungi, and its country of origin. In the literature review, 492 species of mushrooms (wild-growing and cultured) found in 26 European countries and their concentration of 74 associated elements were analysed. The papers, which dealt mainly with the heavy metal (Cd, Cu, Fe, Pb, and Zn) concentrations of mushrooms, primarily came from Turkey, Poland, Spain, and the Czech Republic. More than 50% of the publications provided data about edible mushrooms. The results of the bibliometric analysis showed that over the 16 years, European research on fungal contamination by selected analytes has not lessened in popularity and is ongoing. Many of the studies underlined the need to assess the risk to human health arising from the consumption of contaminated mushrooms taken from various habitats. These results were the effect of, among other things, the strong interest in studies carried out on edible species, in which concentrations of mainly heavy metals that are dangerous to health and are marked were indicated (Cd, Pb, and Hg).All measurements in the paper are to be understood as expressed in mg/m3.In this study, an internal circulation biological aerated filter (ICBAF) reactor was applied to pretreat refinery wastewater containing large amounts of organic pollutants. According