McGrath Francis (sackgalley4)

Finally, nanopapers were validated as heat spreader devices for electronic components, evidencing comparable or better thermal dissipation performance than conventional Cu foil, while delivering over 90% weight reduction.The electroreduction of carbon dioxide is considered a key reaction for the valorization of CO2 emitted in industrial processes or even present in the environment. Cobalt-nitrogen co-doped carbon materials featuring atomically dispersed Co-N sites have been shown to display superior activities and selectivities for the reduction of carbon dioxide to CO, which, in combination with H2 (i.e., as syngas), is regarded as an added-value CO2-reduction product. Such catalysts can be synthesized using heat treatment steps that imply the carbonization of Co-N-containing precursors, but the detailed effects of the synthesis conditions and corresponding materials' composition on their catalytic activities have not been rigorously studied. To this end, in the present work, we synthesized cobalt-nitrogen co-doped carbon materials with different heat treatment temperatures and studied the relation among their surface- and Co-speciation and their CO2-to-CO electroreduction activity. Our results reveal that atomically dispersed cobalt-nitrogen sites are responsible for CO generation while suggesting that this CO-selectivity improves when these atomic Co-N centers are hosted in the carbon layers that cover the Co nanoparticles featured in the catalysts synthesized at higher heat treatment temperatures.While the tremendous deal of efforts has been dedicated to the design and fabrication of materials with circularly polarized luminescence (CPL), the development of the chiroptical switch between different CPL signals is one of the important routes toward its application. Here, we prepared a supramolecular gel from the coassemblies containing a chiral gelator (9-fluoren-methoxycarbonyl-functionalized glutamate derivatives, FLG), a fluorescent molecule [(rhodamine B, RhB) or (2',7'-dichlorofluorescein sodium salt, DCF)], and a photochromic molecule [1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)-3,3,4,4,5,5-hexafluoro-1-cyclopentene, DAE], thus constructing photomodulated switchable CPL soft materials. It was found that FLG could form supramolecular gel in ethanol and self-assemble into left-handed twisted nanostructures. During the formation of a co-gel with RhB (or DCF) and DAE, the chirality of FLG could be effectively transferred to both the fluorescent and photochromic components, which induced them with chiroptical properties including CPL and circular dichroism (CD). DAE undergoes a reversible transition between the achromatous open state and the dark purple closed state in the co-gel under alternating irradiation with UV and visible light. During such a process, an intermolecular Förster resonance energy transfer (FRET) behavior from fluorescent RhB to ring-closed DAE caused the emission quenching of RhB, which led to CPL silence of RhB in the co-gel. Subsequent irradiation with visible light caused the restoration of the emission and CPL activity with the restored open state. These changes could be repeated many times upon alternate UV and visible irradiation. Therefore, a reversible CPL switch was fabricated in supramolecular gels through the photomodulated FRET process.A process to dealloy a Ti-3Zr-2Sn-3Mo-25Nb (TLM) titanium alloy to create a porous surface structure has been reported in this paper aiming to enhance the bioactivity of the alloy. A simple nanoporous topography on the surface was produced through dealloying the as-solution treated TLM alloy. In contrast, dealloying the as-cold rolled alloy created a hierarchical micro/nanoporous topography. SEM and XPS were performed to characterize the topography and element chemistry of both porous structures. The roughness, hydrophilicity, protein adsorption, cell adhesion, proliferation, and osteogenic differentiation were tested. The elements of Zr, Mo, Sn, and Nb were de