Stiles Frantzen (pairserver60)

Effective technologies are needed for the destruction of per- and polyfluoroalkyl substances (PFAS). One promising technology is supercritical water oxidation (SCWO), which can be accommodated in batch or continuous reactors. Many PFAS-laden wastes consist primarily of solid particles, and batch SCWO processing may offer safe end-of-life PFAS destruction for these feedstocks. In this study, perfluorooctanesulfonate (PFOS) is reacted via supercritical water oxidation in a batch reactor at temperatures between 425 and 500 °C and residence times from 0 to 60 min, to determine the effect of both parameters on the extent of destruction and defluorination. Analysis of liquid products via targeted LC-QToF-MS does not indicate production of intermediate fluorocarbons. However, a low fluorine mass balance at temperatures of 425 and 450 °C may indicate the existence of fluorinated species in the gaseous and/or liquid product which are not detected by targeted analysis. Destruction and defluorination efficiencies are determined for each tested condition, with a maximum 70.0% PFOS destruction and 78.2% defluorination achieved after 60 min of reaction at 500 °C.Contamination of water by nitrate has become a worldwide problem, being high levels of this ion detected in the surface, and groundwater, mainly due to the intensive use of fertilizers, and to the discharge of not properly treated effluents. This study aims to evaluate the electrocatalytic process, carried out in a cell divided into two compartments by a cation exchange membrane, and with a copper plate electrode as cathode, identifying the effects of current density, pH, the use of a catalyst in the nitrate reduction, and the production of gaseous compounds. The highest nitrate reduction was obtained with a current density of 2.0 mA cm-2, without pH adjustment and, in this condition, nitrite ion was mainly formed. The application of activated carbon fibers with palladium (1% wt. and 3% wt.) in an alkaline medium presented an increase in gaseous compounds formation. With 2.0 mA cm-2, pH adjustment, and applying 3% wt. Pd catalyst, the highest selectivity to gaseous compounds was obtained (95%) with no nitrite detection. These results highlight the viability of using the process developed at this work for the treatment of nitrate contaminated waters.To improve the remediation efficiency of plants on low concentration uranium-bearing wastewater and clarify its strengthening mechanism, Syngonium podophyllum-Peperomia tetraphylla co-planting system was established, the enhanced effects of plants interaction on uranium removal were investigated, the chemical forms, valence states, and subcellular distribution of uranium in plants were confirmed, and the mechanisms of alleviating uranium stress by plants interaction were revealed. In Syngonium podophyllum-Peperomia tetraphylla co-planting system, the total amount of ethanol-extracted uranium and deionized water-extracted uranium with higher toxicity in their roots were reduced by 10.30% and 7.17%, respectively, which reduced the toxicity of uranium to plants. Plants interaction can inhibit the reduction of U(VI) in the root of Peperomia tetraphylla, which is conducive to the transport of uranium from roots to shoots. BI-1347 datasheet In addition, uranium in plants mainly existed in the cell wall (54.44%-66.52%) and the soluble fraction (23.85%-32.89%). These results indicated that Syngonium podophyllum and Peperomia tetraphylla co-planting can enhance their effects of uranium removal by alleviating uranium stress with the cell wall immobilization and vacuole compartmentation, improving biomass of plants, increasing bioaccumulation factor and translocation factor of uranium.Sex-ratio is considered as an end point during endocrine disrupting chemicals (EDCs) evaluation. Many fish species including Japanese medaka have XX/XY sex determination mechanism, however, sex reversal (SR) can be induced by external and genetic factors. SR impose