Medeiros Duelund (miceliver2)

The effect of atomic hydrogen adsorption on AnO2 (An = Th, U, and Pu) surfaces is studied in the framework of density functional theory and Hubbard-corrected density functional theory. Several adsorption coverages (1/3, 1/2, 2/3, and 1 monolayer) are considered. For the band insulator ThO2, surface metallicity induced by hydrogen adsorption is observed due to the electron donation of the hydrogen to the surface. But this effect is found to be strongly suppressed by electronic correlation for the Mott insulators UO2 and PuO2 because the electrons from the adsorbed hydrogen atoms occupy the localized 5f orbitals of the surface U/Pu atoms.In-plane anisotropic two-dimensional (2D) materials possess unique in-plane anisotropic physical properties arising from their low crystal lattice symmetry. Among these low-symmetry 2D materials, anisotropic Ge-based binary materials have the advantages of simple binary and earth-abundant compositions, good stability, highly anisotropic physical properties along two principle axes, and wide coverage of bandgaps, enabling use in broadband photodetection from the infrared to ultraviolet region. GPCR antagonist Here, we review recent progress in in-plane anisotropic 2D Ge-based binary materials, focusing on their anisotropic structural, electrical and optical properties. We then discuss demonstrations of optoelectronic applications related to those anisotropic properties including polarization-sensitive photodetection and polarization-based all-optical switches. Finally, we provide further possible opportunities for this relatively new, but quickly expanding family of materials.Herein, a new colorimetric sensor array was developed for the first time, which can rapidly recognize 9 types of metal ions (e.g., Ni2+, Zn2+, Cd2+, Cu2+, Cr3+, Fe2+, Se2+, Mn2+, and Mg2+). The colorimetric characteristics of the sensor array were closely related to the oxidation etching of the triangular gold nanoplates (AuNPLs) by hydrogen peroxide (H2O2), catalyzed by horseradish peroxidase (HRP). In the design, two types of thiols (glutathione (GSH) and cysteine (Cys)) as recognition elements were employed to construct the sensor units (AuNPLs/GSH and AuNPLs/Cys) and adjust the etching degrees of AuNPLs in the presence of various metal ions. The differential binding affinities between metal ions and thiols will lead to different degrees of oxidation etching of AuNPLs with hydrogen peroxide, exhibiting characteristic colors, which can be visually distinguished by the naked eye. Thus, the colorimetric sensor array provides a new way for the discrimination of various metal ions, thereby simplifying the water quality analysis.In this paper, we examine a new method for isotope separation involving the embedding of atoms and molecules into ice. This method is based upon isotope dependent embedding, i.e. capture, in a cryogenic matrix which exhibits excellent single-pass enrichment as demonstrated successfully for selected isotopes of Xe. This is a totally new method that holds significant promise as a quite general method for enrichment and purification. It is based upon exploiting the energetic and momentum barriers that need to be overcome in order to embed a given isotope or isotopologue into the capture matrix, initially amorphous ice. From our previous experiments, we know that there is a strong dependence of the embedding probability with incident momentum. Using supersonic molecular beam techniques, we generated Xe atomic beams of controlled velocities, relatively narrow velocity distributions due to supersonic expansion, and with all of the entrained isotopes having identical velocities arising from the seeded molecular beamotential impact for a wide-variety of isotope-based technologies in the physical and biological sciences, medicine, advanced energy and energetic systems, including isotopically-purified materials that exhibit high-performance electronic and thermal characteristics, as well as isotopically purif