Ross Dohn (lizardcod7)
24 and 0.73 for mid- and late season stages, respectively for standard conditions. H-151 FAO segmented and second-order polynomial functions are presented to describe the crop coefficient evolution throughout the cycle, and could be used for irrigation scheduling and may lead to important water savings. The average seasonal net irrigation water requirement for chufa crop was approximately 640 mm, representing around 57% of the irrigation depth usually applied by chufa growers. The water savings that may be achieved by the adjustment of irrigation water with irrigation water requirements, using the crop coefficient, would improve, to a great extent, the sustainability of the L'Horta de València historical agricultural system, in view of the water scarcity resulting from climate change. This sustainable irrigation scheduling will improve the ecosystem indices, which have been altered by the application of over-irrigation, in the area.In this work, we have experimentally and computationally investigated the process of hydrolysis and photolysis of cephalosporin antibiotics with ceftriaxone (CEF) as a model compound. The CEF hydrolysis was investigated in ultrapure and natural water, at 25 ± 1 °C and 4 ± 1 °C in the dark. It was found that CEF after 100 and 900 days at 25 ± 1°C and 4 ± 1 °C, respectively practically completely removed from ultrapure water. The CEF hydrolysis in natural water was five and three times slower at 25 ± 1 °C and 4 ± 1 °C, respectively than in ultrapure water. Further, the efficiency of direct photolysis (solar/UVA-B) and solar/H2O2 treatment of CEF was investigated. Under UVA-B radiation 95.6% of CEF was removed after 60 min, while for the same time of solar radiation degradation was practically not observed (only 3.2%). Also, the effects of different concentrations of H2O2 (0-150 mM) in the presence/absence of solar radiation were studied. The most efficient solar/H2O2 treatment was in the presence of 90 mM H2O2, whereby 66.8% of CEF was removed after 60 min (41.8% by indirect photolysis, 21.8% by H2O2-oxidation, and 3.2% by direct photolysis). Radial distribution functions (RDF) provided information about the distribution of water around the CEF molecule. Aside from the RDF, investigation of intramolecular noncovalent interactions and calculations of bond dissociation energies for hydrogen abstraction enabled understanding of degradation mechanism of CEF. In order to investigate sensitivity of CEF towards the radical attacks, the concept of Fukui functions was used. The structures of intermediates and degradation pathways were suggested by UHPLC-LTQ OrbiTrap MS and density functional theory calculations. Toxicity assessments showed that intermediates formed during hydrolysis exerted only mild cell growth effects in selected cell lines.Coastal hypoxia/anoxia is a major emerging threat to global coastal ecosystems. Macroalgae blooms of tens of kilometers are often observed in open waters. These blooms not only cause a lack of oxygen, but also benthic light limitation. We explored the physiological responses of Zostera marina L. to anoxia under darkness. After exposing Z. marina to anoxia under darkness for 72 h, we measured the elongation of leaves and the decrease in maximal quantum yield of photosystem II (Fv/Fm), and investigated the transcriptomic and metabolomic responses to anoxic stress based on RNA-sequencing and liquid chromatography-mass spectrometry (LC-MS) technology. The results showed that anoxic stress significantly reduced the leaf Fv/Fm, and had a significant negative effect on the photosynthesis and growth of Z. marina. Kyoto Encyclopedia of Genes and Genomes (KEGG) pathway enrichment analysis of up-regulated differentially expressed genes (DEGs) showed that glycolysis was the most significant enrichment pathway (p less th-aminobutyric acid (GABA) shunt mechanisms, were detected in the leaves, while GABA and alanine were not detected. The results of this study show that anoxic stres
