Wiberg Dam (lambchord99)
In addition, a comparison of the 2019 data set to occurrence data collected for German formulas purchased in 2015 showed that average bound 3-MCPD and glycidol concentrations have decreased (from 0.094 to 0.054 µg g-1 and from 0.010 to 0.006 µg g-1, respectively), likely indicating that additional/improved mitigation measures for reducing contaminant concentrations in infant formulas have been implemented over the 4-year period. The data collected in this occurrence study are suitable for estimating levels of exposure to these compounds for German infants.Abbreviations 2-MCPD 2-monochloropropane-1,3-diol; 3-MCPD 3-monochloropropane-1,2-diol; ARA arachidonic acid; CE collision energy; CXP collision cell exit potential; DHA docosahexaenoic acid; DP declustering potential; EP entrance potential; EPA eicosapentaenoic acid; EtOAc ethyl acetate; IPA isopropanol; LC-MS/MS liquid chromatography-tandem mass spectrometry; MeOH methanol; MTBE methyl tert-butyl ether; SPE solid-phase extraction.Polyesters labelled as bio-based or compostable are increasingly common among the 'bioplastics' in use as food contact materials (FCM). The knowledge of material composition is mandatory to predict potential leachable oligomers as well as to partly evaluate the correctness of the label 'bioplastic', which is used for promotional purposes. The composition of (bio)polyesters can be determined by alkaline hydrolysis of the entire material and subsequent analysis of the monomers via high-performance liquid chromatography with diode array detection and GC-MS detection. Thirty-three frequently used monomers (polycarboxylic acids, hydroxy carboxylic acids, polyols) including highly polar monomers such as lactic acid were analysed with detection limits below 10 g/kg of the material. Lactic acid enantiomer elucidation was performed using an enzyme assay. The content of non-hydrolysable residue was determined gravimetrically after hydrolysis, and the inorganic residue after washing. The composition of 12 polyesters mostly in food contact, labelled as bio-based or compostable and sampled from the market was elucidated recovering 92-101% of the total mass by summing up the determined monomers and non-polyester contents. Seven different monomers were detected in the 12 samples (up to four different monomers per sample), lactic acid being the most common (9 samples) with contents ranging from a minor component (about 11 mol%) up to the only monomer found in the material. The ratio of d- to l-lactic acid ranged from 0.399.7 to 4.795.3 (w/w). The non-hydrolysable (in)organic residue was quantified in amounts of up to 390 g/kg. Overall, the presented analytical protocol is a fundamental tool helping both to verify the appropriateness of labelling as biopolyesters as well as to predict potential leachables such as oligomers during an FCM risk assessment.Microplastic pollution of inland environments has been receiving increased publicity over the last few years. NVL-655 price For the first time, this study reports on the presence of microplastics (0.1 mm to less then 5 mm) in the gastrointestinal tracts of Alburnus tarichi in Lake Van from January to April 2020. In total, 101 fishes were obtained from Citoren, Edremit, Gevas and Dagonu fisheries regions. A total of 3338 pieces of plastic, ranging from 8 to 124 samples per fish with averaging 34 ± 13 MPs/individual, were extracted from gastrointestinal tracts of fish. The majority of the ingested particles consisted of fibres (74%), and blue coloured material was the most consumed microplastic. The polymers identified by Fourier Transform Infrared Spectroscopy (FTIR) were polyethylene and polypropylene. Consequently, this study suggested that the vast majority of A. tarichi were contaminated with microplastics and showed higher abundance in comparison with other worldwide studies so far.In this study, a novel sorbent, 1-octyl-3-methylimidazolium hexafluorophosphate functionalised magnetic poly β-cyclodextrin, was
