Quinlan Pedersen (kevindinner96)

This work aimed to study the stabilization mechanism induced by different morphologies of cellulosic fiber in O/W emulsion. Three types of cellulosic fibers were named squashed cellulose, incompletely nanofibrillated cellulose, and completely nanofibrillated cellulose, respectively. Squashed cellulose acted as barriers between the droplets to stabilize emulsion via depletion flocculation, whereas incompletely nanofibrillated and completely nanofibrillated cellulose formed covering layer via interfacial adsorption and connected adjacent droplets to create the droplet-fiber network structure via bridging flocculation. Differently, completely nanofibrillated cellulose formed the denser covering layer leading to a more stability of droplet. Importantly, it had the higher capacity of bridging flocculation, which can tightly connect the adjacent droplets to form a stronger droplet-fiber 3D network structure. Consequently, in rheological analysis including creep compliance, and dynamic modulus, the corresponding emulsions showed excellent anti-deformation ability and dynamic stability. This study provides practical guidance on the productions of foodstuff and cosmetic.A series of cationic starches with different degrees of substitution were synthesized by etherification of potato starch with 3-chloro-2-hydroxypropyl trimethylammonium chloride (CTA). Cationic starch nanoparticles (CTA-StNPs) with different sizes were prepared by precipitation. Flocculation behaviors of the CTA-StNPs in simulated water sample containing kaolin were studied. The results showed that the dosage required to bring the simulated water sample containing kaolin to attain maximum transmittance at pH = 4 was significantly less than that at pH = 7. Both the size and degree of substitution of the CTA-StNPs affected their flocculation performance. The smaller the size and the higher the degree of substitution of CTA-StNPs, the better was the flocculation performance. Charge neutralization played a leading role in the flocculation process. read more The adsorption process of the CTA-StNPs onto kaolin could be divided into rapid adsorption, stable adsorption and equilibrium adsorption and followed pseudo second-order kinetic equation very well (R2 > 0.99).A pot experiment was conducted to explore the effects of high-quality (Huanghuazhan, HH), drought-resistant (IR, IRAT109) and drought-susceptible cultivars (ZS, Zhenshan97) under flooding irrigation and dry cultivation (D) on the starch accumulation and synthesis, physicochemical traits of starch granules and rice grain quality at the upper (U) and lower panicle. Under D treatment, IR and ZS had lower rice quality, especially the appearance and cooking quality. DHH-U had the highest appearance, nutritional and cooking quality among all cultivars under D treatment, which could be ascribed to the synthesis of more short-branch chain amylopectin and correspondingly higher starch granule tightness. DHH-U also maintained ordered carbohydrate structure, crystalline regions, and many hydrophilic and hydrophobic functional groups in starch granules before pasting. It could prevent the polymerization of small molecules to avoid the formation of macromolecules after pasting. Overall, these findings may facilitate the improvement of grain quality in rice dry cultivation.Recently, the hydrogel-forming polysaccharide gellan gum (GG) has gained popularity as a versatile biomaterial for tissue engineering purposes. Here, we examine the modification strategies suitable for GG to overcome processing-related limitations. We emphasize the thorough assessment of the viscoelastic and mechanical properties of both precursor solutions and final hydrogels. The investigated modification strategies include purification, oxidation, reductive chain scission, and blending. We correlate polymer flow and hydrogel forming capabilities to viscosity-dependent methods including casting, injection and printing. Native GG and purified NaGG are s