Churchill Vedel (courseshorts2)

Although Cu concentration increased in leaves by foliar spray of CuO NPs, it remained safe for consumption.In this study, we evaluated indoor air quality to highlight the effects of environmental pollution in the field of cultural heritage. In particular, two important archeological places in the old part of the city of Salerno, Italy, were analyzed Fruscione Palace and S. Pietro a Corte. The work focused on the influence of tourists on environmental pollution correlated to indoor air quality during some social and cultural events. Moreover, we focused on the possible use of the carbon isotopic composition of CO2 as a tool for environmental studies in the field of cultural heritage. The results showed a good relationship between the isotopic composition of CO2 and the variation of pollutants concentration in the air, demonstrating that it is a valid tool and non-invasive marker to monitor environmental pollution of museums and cultural heritage sites.In this study, Mg-modified sludge biochar (MB) and Mg-Fe double oxides/sludge biochar composites (MFB) were synthesized for enhanced removal of phosphate from aqueous solution. The phosphate adsorption followed the Langmuir-Freundlich isotherm model, and the maximum capacity was 142.31 mg P/g and 35.41 mg P/g for MB and MFB, respectively. MB exhibited the higher adsorption capacity at pH 8-9 and performed well under the influences of coexisting anions and temperature (4-45 °C). Adsorption kinetics was well described by the pseudo-second-order kinetic model, indicating the chemical bonding between phosphate and adsorption sites. The adsorption capacity of phosphate decreased by less then 15% after three successive recycles. Based on FTIR, XRD, and XPS analysis, the main mechanisms for phosphate removal by MB included electrostatic attraction, surface complexation, and precipitation. Hydroxides/oxides particles of Mg on the surface of MB with positive charge could adsorb HPO42- and PO43- to form surface complex and convert to MgHPO4 and Mg3(PO4)2. The released amounts of Fe, Cd, Cr, Pb, Cu, Zn, Sb, and As from MB and MFB were low and acceptable. However, the released amount of Mg was as high as 4.9 wt% for MB and 8.7 wt% for MFB at the pH corresponding maximum adsorption capacity, posing a risk of salt increase. The grass (Lolium perenne L.) germination and early growth with the addition of P-laden biochars as fertilizer are seriously inhibited due to the high alkalinity, particularly for MB. The environmental risk of P-laden biochars (with high alkalinity and salt content) as fertilizer should be emphasized in practical application.Within a short period, rapid urbanization has reshaped China's eco-environment, especially at the beginning of the new century. Many studies have focused on the changes in certain physical indicators of eco-environments; however, these indicators cannot directly explain or only slightly consider the eco-environmental benefits of urban residents. Therefore, we analysed location-based population-weighted eco-environmental changes with indicators of the vegetation index and fine particulate matter (PM2.5) concentration at each pixel in China's prefectures and combined the changes with urban expansion to provide an expanded understanding of the transformation of China's urbanization and its eco-environmental dynamics. We discovered that China's urban areas expanded by 38,350 km2 from 2000 to 2015 with an increase in the population-weighted vegetation and PM2.5 concentration, but the changes varied among different periods. From 2005 to 2010, urban areas expanded by 20,970 km2 with an increase in the population-weighted vegetation and PM2.5 concentration. The period from 2000 to 2005 was a key transforming period that experienced an urban expansion of 9081 km2 with a decrease in the population-weighted vegetation and an increase in the population-weighted PM2.5 concentration. An urban expansion of 8299 km2 with an increase in the population-weighted vegetati