Branch Skaarup (arrowbonsai58)

Volatile organic compounds (VOCs) play a vital role in the global carbon budget and in the regional formation of ozone in the troposphere, and are emitted from both natural and anthropogenic activities. They can also serve as a source of secondary organic aerosol (SOA). Field and model studies showed evidences of a strong marine biogenic influence on marine aerosols. Although knowledge of terrestrial VOC emissions and SOA formation mechanisms has been advanced considerably over the last decades, processes constraining marine VOC emissions and marine SOA formation remain poorly understood. Seawater contains an extremely complex, diverse, and largely unidentified mixture of VOCs. Despite the fact that the ocean covers 70% of the Earth's surface, the role of the ocean in the global budget of VOCs is still unclear. Pixantrone The distribution and emission of sea surface VOCs exhibit considerable spatial-temporal variation, with higher concentrations often, but not always, correlated with biological activities. VOCs in surface seawater have been measured in various geographic regions, however, knowledge of the distribution of marine VOCs and the role of the oceans in the global atmospheric chemistry is still insufficient due to the paucity of measurements. This study reviews marine VOCs in terms of current analytical methods, global marine VOCs measurements, their effects on SOA, and future needs for understanding the role of marine VOCs in the chemistry of the atmosphere.Studying the behaviour of nanomaterials after their release into natural water is essential to understand the risk associated to their environmental exposure. In particular, the interaction and adsorption of dissolved organic matter onto nanoparticles strongly influence the behaviour and fate of nanomaterials in natural water systems. We herein study the interaction of Au and Ag nanoparticles and humic acids, the principal component of natural dissolved organic matter. Physicochemical characterization results showed the formation of an organic matter corona, consisting of two layers a "hard" one, firmly bound to the nanoparticle surface, and a "soft" one, in dynamic equilibrium and, consequently, highly dependent on the media organic matter concentration. The extent of the electro-steric stabilization of the so called environmental corona depends on the size of the supramolecular association of humic acid (which depends on its hydrophilic and lipophilic moieties), the nanoparticle size, the total concentration of organic matter in the media, and the ratio between them. Interestingly, environmental coronas can eventually prevent Ca2+ and Mg2+ induced aggregation at concentrations range present in most of the freshwater bodies. The humic coating formed on top of the Au or control Ag nanoparticles presented a similar profile, but the corrodibility of Ag led to a more natural detachment of the corona. These results were further confirmed by exposing the nanoparticles to a model of natural water and standard mud (LUFA 2.2 dispersion). In the latter case, after several days, nanoparticle sedimentation was observed, which was attributed to interactions with macro organic and inorganic matter (fraction larger than particulate matter).Freshwater lenses connect the terrestrial and marine realm via groundwater discharge at the edges of islands and serve as drinking water resources. We studied the redox-sensitive metals U, Mo, V, and Tl along the redox gradient of fresh groundwater lenses on Spiekeroog Island, northern Germany. Groundwater solute concentrations were linked to groundwater age and redox characteristics. We further quantified the contribution of precipitation, sea spray, and aquifer matrix to the groundwater metal concentrations and evaluated the sink and source function of the aquifer under oxic and reducing conditions. We found that biogeochemical processes altered the concentrations of the trace metals. In young, oxygen to nitrate reducing zones, the aqui